From LedHed's Wiki
WMIC
This command will return the name of the user who is currently logged into the console.
Note: It does not return the names of users who are connected via RDP.
WMIC /NODE: "workstation_name" COMPUTERSYSTEM GET USERNAME
Command Line
To see a list of remote connected users run this command:
qwinsta
or for a list of remote connected users on another server:
qwinsta /server:<SERVER_HOSTNAME>
or
query.exe user /server:<SERVER_HOSTNAME>
Where <SERVER_HOSTNAME> is the hostname of the server you want to check.