From LedHed's Wiki
Stop the W32Time service:
net stop w32time
Configure the external time sources:
w32tm /config /syncfromflags:manual /manualpeerlist:â0.pool.ntp.org, 1.pool.ntp.org, 2.pool.ntp.orgâ
Make your PDC a reliable time source for the clients:
w32tm /config /reliable:yes
Start the w32time service:
net start w32time
The windows time service should begin synchronizing the time.
Check the external NTP servers in the time configuration by typing:
w32tm /query /configuration